Radioactivity in food

The ifp institute for product quality offers the examination of food for radioactivity. The determination of radioactivity in food is performed gamma-spectroscopically using a coaxial germanium detector, which is cooled with liquid nitrogen to avoid thermally induced noise signals. We analyse the gamma spectrum routinely.  for the isotopes relevant in food. These are primarily:

• ¹³¹I (iodine-131)
• ¹³⁴Cs (caesium-134)
• ¹³⁷Cs (caesium-137)

Their activity is recorded in Bq/kg. The detection limit varies depending on the duration of the analysis and the isotope, but is far below the legally defined maximum limit. Further information on radioactivity can be found here:

• Theory of radioactivity

Background

As a result of the Chernobyl reactor catastrophe in 1986, the European Atomic Energy Community (EURATOM) adopted legal regulations at European level for food and feed to protect the population from contaminated food and feed.

Regulation (EURATOM) No 3954/87 established maximum permitted levels of radiation in foodstuffs and feedingstuffs in the event of a nuclear accident or any other case of radiological emergency.

Foodstuffs of minor importance were additionally defined in Regulation (EURATOM) No 944/89 and corresponding maximum permitted levels were established. Maximum permitted levels for feedingstuffs were additionally set in Regulation (EURATOM) No 770/90.

In addition, Regulation (EC) No 733/2008 on the conditions for the importation of agricultural products originating in third countries following the accident at the Chernobyl nuclear power plant also regulated specific maximum levels for goods from the areas contaminated by the nuclear disaster.

Fukushima

In response to the serious reactor accident that occurred in Fukushima, Japan, in March 2011, Regulation (EU) No 297/2011 was issued. According to this emergency regulation, food and feed imports from the affected Japanese prefectures were initially subject to the maximum levels of iodine-131, caesium-134 and caesium-137 established in Regulations No 3954/87, 944/89 and 770/90, and shortly thereafter, this regulation was amended by Regulation (EU) No 351/2011, in Annex II of which new maximum levels were established in accordance with the levels in Japan.

Currently

In January 2016 a new Euratom Regulation laying down maximum permitted levels of radioactive contamination of foodstuffs and of feedingstuffs which may be contaminated with radioactive substances following a nuclear accident or any other case of radiological emergency was adopted (Regulation (Euratom) 2016/52). This applied from February 2016.

This regulation authorizes the Commission to set binding maximum permitted levels in a regulation at short notice following a radiological emergency. This makes it possible to adapt the maximum permitted levels for radioactivity in food and feed quickly and flexibly to the circumstances of the respective emergency. However, these may not exceed the maximum levels established in the annexes to the regulation.

The possibility of setting lower permitted levels is intended to optimise radiation protection and keep the radioactive exposure of the population as low as reasonably achievable in an emergency.

Regulation (Euratom) 2016/52 thus enables effective protection of the European population from radioactively contaminated food and also limits the use of contaminated feed for this purpose. It replaces the previously valid Euratom Regulations No. 3954/87, No. 944/89 and No. 770/90.

Theory of Radioactivity

Radioactivity is the property of unstable atomic nuclei to transform spontaneously. The process releases energy (usually by emitting ionizing radiation). In general terms, radiation is the emission of particles or energy. Ionizing radiation is capable of removing electrons from atoms or molecules, leaving behind positively charged cations.

Structure of the atom

An atom consists of the positively charged atomic nucleus and a negatively charged electron shell. The positive charge of the nucleus is due to the protons. The number of protons (atomic number Z) is specific to each chemical element. Carbon (C), for instance, has six protons, nitrogen (N) has seven.

Outwardly atoms are neutral, since the positive charges of the protons are compensated by the same number of negatively charged electrons in the atomic shell. An atom that has more or less electrons than protons is referred to as a (charged) ion.

Along with the protons, the atomic nucleus also contains uncharged (neutral) neutrons. Usually the number of neutrons (N) equals the number of protons, i.e. the atomic number (Z). Both together result in the mass number (A):

A = N + Z

The various types of atoms (nuclides) differ by their mass number, atomic number and neutron number. Nuclides with identical atomic numbers but different neutron numbers are referred to as isotopes. There are two stable isotopes of carbon, for instance: carbon-12 (¹²C) with six, and carbon-13 (¹³C) with seven neutrons.

Types of radiation

Alpha radiation

When an atomic nucleus decays, an alpha particle (helium nucleus), consisting of two protons and two neutrons, is emitted. As a result the atomic number is reduced by two and the mass number by four.  This is how ²¹⁰Po (Z = 84) transforms into ²⁰⁶Pb (Z = 82) by emitting a helium nucleus.

Beta radiation

In the event of a beta^- decay a neutron transforms into a proton and an electron is emitted. The atomic number increases by one. Example: ¹⁹⁸Au (Z = 79) transforms into ¹⁹⁸Hg (Z = 80) as a result of one electron being emitted.

If a proton transforms into a neutron, a positron is emitted. This is referred to as a beta⁺ decay. The atomic number decreases by one.

Gamma radiation

Gamma radiation usually occurs as a direct result of alpha or beta decay. If, after such decay, the atomic nucleus is in an excited state, a gamma quantum will be emitted in the process of transition to the energetically more favourable basic state. The mass number and the atomic number remain unchanged during this process.

Biological effects and penetration capacity

Due to relatively large particles being released in the event of alpha radiation, the ionizing effect, i.e. harmfulness to biological tissue, is particularly high in this case. At the same time alpha radiation has the lowest penetration capacity and can be shielded by as little as a piece of paper. Beta radiation can only spread a few millimetres in solid bodies. It can be shielded by a timber board, for example. Gamma radiation has the highest penetration capacity, yet no defined range. Instead it is diminished depending on the shielding material and the material’s thickness.

Physical quantities and units

Activity

Activity (A) is the amount of radiation emitted within a certain period of time. The unit is becquerel (Bq). 1 Bq equals one nucleus decay per second. Since the activity also depends on the number of unstable atomic nuclei in a given sample, the radioactivity of food is specified in relation to its mass and given in Bq/kg.

Absorbed dose

The absorbed dose (total ionising dose, TID) is the energy (joule per kilogramme) absorbed by a medium per unit mass. The unit used in this case is gray (Gy). The following applies:

1 Gy = 1 J/kg

Further dosimetric quantities

The detrimental effect of an energy dose on biological tissue varies with the type of radiation that causes it and with the organs that absorb it. Dimensionless quality or weighting factors are therefore used when multiplying in order to calculate the equivalent, organic or effective dose, for example. These weighted doses are specified in J/kg. In order to distinguish them from the absorbed dose, they are specified in sievert (Sv) instead of gray.

1 Sv = 1 J/kg

Consumption of radioactively contaminated foods

The German Federal Office for Radiation Protection states that ingesting 80,000 Bq caesium-137 (¹³⁷Cs) from contaminated food equals a radioactive exposure of approx. 1 mSv (millisievert) in adults.

Consuming a 200 g portion of mushrooms containing 4,000 Bq/kg hence leads to a radiation exposure of 0.01 mSv. For comparison: the natural radiation exposure in Germany is approx. 2.1 mSv per year.